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- In the same microwave plasma-increased CVD position, the new decisions away from carbon dioxide on the Fe-Cr-Al steel substrate as well as on the newest Fe-Cr-Ni metal substrate try completely different.
Shape 10.
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- While the grounds commonly well-understood, variations in the brand new atomic design, like the quantity of nitrogen atoms present are believed in order to sign up for the newest phenomenon.
Then the catalytic formation of graphite from the iron, cobalt aspects throughout the CVD diamond try made clear. Profile step 1 suggests an example of significant internal carburization about the metal substrate Hot Ink slot which was met with a good CH4/H2 combination around 670 °C through the CVD diamond movies. The brand new browsing electron microscopy (SEM) image within the Shape 1a shows the brand new morphology of large graphite preferentially formed ahead of diamond deposition. The fresh decomposition away from an excellent metastable Fe3C carbide layer is an important sum so you can graphite creation, that’s analogous to the well-identified aftereffect of material dusting for the iron foot substrates 21,22,23. You will find shown one to diamond movies can be produced within the a good closed sexy filament CVD program.
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